Tri-X for documentary and Velvia for landscape are classic choices, no doubt about that.
For slide film, Velvia is a tough one to work with - it won't tolerate exposure errors and can be time consuming to get a good scan from (in my experience). Fuji's Provia 100F is a little easier to work with although any slide film really needs very exact exposure. Provia has very little reciprocity failure to work with, makes most colors (including skin tones to some extent) look good but you'll probably want an 81A and/or 81B filter (warming) because it has a tendancy to be a little blue-ish.
Are you going to develop your own b&w film? It's really not hard if you haven't done it before. Tri-X and Kodak's D-76 developer is an easy combination to use, just do it "by the book". It's a classic look that (again, IMO) doesn't really come across in digital. From there, you can scan the negatives and print yourself or take to a lab. If you're not developing yourself, I'd probably try some of the C41 color process b&w films that are out there. Can't remember what Kodak's latest version of it is, but this type of film usually scans really well. True b&w processing can be a little hard to find at a lab.



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