Personally, I use Adobe GoLive, but have an older version of DW on disc somewhere...

We've discussed this before, and there's no doubt DW is a really good web design program. Most of us who use GL do so simply because it fits in better with other Adobe software such as Photoshop and Illustrator.

I did have DW on my pc for a while and made an effort to learn it, but this was when I had aspirations of being a rich and famous web designer (uh, never happened, sniff!). Now, I find I just can't dilute my time to learn both programs...

I say go for it. There will be lots of stuff you pick up that you'll be able to apply to web design in general and certainly other web programs if you choose to switch to them later...